View in EDS

Oxorhenium Complexes for Catalytic Hydrosilylation and Hydrolytic Hydrogen Production: A Multiweek Advanced Laboratory Experiment for Undergraduate Students

Saved in:
Bibliographic Details
Title: Oxorhenium Complexes for Catalytic Hydrosilylation and Hydrolytic Hydrogen Production: A Multiweek Advanced Laboratory Experiment for Undergraduate Students
Language: English
Authors: Ison, A. (ORCID 0000-0001-9622-4372), Ison, E. A. (ORCID 0000-0002-2902-2671), Perry, C. M.
Source: Journal of Chemical Education. Jun 2017 94(6):790-794.
Availability: Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Peer Reviewed: Y
Page Count: 5
Publication Date: 2017
Intended Audience: Teachers
Document Type: Journal Articles
Reports - Descriptive
Education Level: Higher Education
Postsecondary Education
Descriptors: Science Instruction, College Science, Undergraduate Study, Chemistry, Scientific Concepts, Kinetics, Spectroscopy, Teaching Methods, Laboratory Experiments, Science Experiments, Science Laboratories
Geographic Terms: North Carolina
DOI: 10.1021/acs.jchemed.6b00954
ISSN: 0021-9584
Abstract: An effective way of teaching undergraduates a full complement of research skills is through a multiweek advanced laboratory experiment. Here we outline a comprehensive set of experiments adapted from current primary literature focusing on organic and inorganic synthesis, catalysis, reactivity, and reaction kinetics. The catalyst, bis(2-(2'-hydroxyphenyl)-2-oxazoline)oxorhenium(V) tetrapentafluorophenylborate (1) is isolated through a multistep reaction starting with the formation of the ligand, 2-(2'-hydroxyphenyl)-2-oxazoline (2), followed by complexation of a Re-oxo precursor to form chlorobis(2-(2'-hydroxyphenyl)-2-oxazoline)oxorhenium(V) (3). Both Re(V)-oxo complexes are diamagnetic and allow for NMR analysis. Complex 1 is an air-stable and highly active catalyst for two reactions: (1) hydrosilylation of carbonyls and (2) hydrolysis of Et[subscript 3]SiH to form Et[subscript 3]SiOH and H[subscript 2] gas. Students monitor the evolution of hydrogen gas in the second reaction and use the data to investigate the reaction kinetics in order to obtain the complete rate law and the second-order rate constant for the catalytic reaction. The complete project provides a wealth of opportunities to focus on experimental skills, fundamental concepts in inorganic and organic chemistry, catalysis, reactivity, and experimental kinetics.
Abstractor: As Provided
Number of References: 22
Entry Date: 2017
Accession Number: EJ1145960
Database: ERIC
FullText Text:
  Availability: 0
Header DbId: eric
DbLabel: ERIC
An: EJ1145960
AccessLevel: 3
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Oxorhenium Complexes for Catalytic Hydrosilylation and Hydrolytic Hydrogen Production: A Multiweek Advanced Laboratory Experiment for Undergraduate Students
– Name: Language
  Label: Language
  Group: Lang
  Data: English
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Ison%2C+A%2E%22">Ison, A.</searchLink> (ORCID <externalLink term="http://orcid.org/0000-0001-9622-4372">0000-0001-9622-4372</externalLink>)<br /><searchLink fieldCode="AR" term="%22Ison%2C+E%2E+A%2E%22">Ison, E. A.</searchLink> (ORCID <externalLink term="http://orcid.org/0000-0002-2902-2671">0000-0002-2902-2671</externalLink>)<br /><searchLink fieldCode="AR" term="%22Perry%2C+C%2E+M%2E%22">Perry, C. M.</searchLink>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="SO" term="%22Journal+of+Chemical+Education%22"><i>Journal of Chemical Education</i></searchLink>. Jun 2017 94(6):790-794.
– Name: Avail
  Label: Availability
  Group: Avail
  Data: Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
– Name: PeerReviewed
  Label: Peer Reviewed
  Group: SrcInfo
  Data: Y
– Name: Pages
  Label: Page Count
  Group: Src
  Data: 5
– Name: DatePubCY
  Label: Publication Date
  Group: Date
  Data: 2017
– Name: Audience
  Label: Intended Audience
  Group: Audnce
  Data: Teachers
– Name: TypeDocument
  Label: Document Type
  Group: TypDoc
  Data: Journal Articles<br />Reports - Descriptive
– Name: Audience
  Label: Education Level
  Group: Audnce
  Data: <searchLink fieldCode="EL" term="%22Higher+Education%22">Higher Education</searchLink><br /><searchLink fieldCode="EL" term="%22Postsecondary+Education%22">Postsecondary Education</searchLink>
– Name: Subject
  Label: Descriptors
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Science+Instruction%22">Science Instruction</searchLink><br /><searchLink fieldCode="DE" term="%22College+Science%22">College Science</searchLink><br /><searchLink fieldCode="DE" term="%22Undergraduate+Study%22">Undergraduate Study</searchLink><br /><searchLink fieldCode="DE" term="%22Chemistry%22">Chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Scientific+Concepts%22">Scientific Concepts</searchLink><br /><searchLink fieldCode="DE" term="%22Kinetics%22">Kinetics</searchLink><br /><searchLink fieldCode="DE" term="%22Spectroscopy%22">Spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Teaching+Methods%22">Teaching Methods</searchLink><br /><searchLink fieldCode="DE" term="%22Laboratory+Experiments%22">Laboratory Experiments</searchLink><br /><searchLink fieldCode="DE" term="%22Science+Experiments%22">Science Experiments</searchLink><br /><searchLink fieldCode="DE" term="%22Science+Laboratories%22">Science Laboratories</searchLink>
– Name: Subject
  Label: Geographic Terms
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22North+Carolina%22">North Carolina</searchLink>
– Name: DOI
  Label: DOI
  Group: ID
  Data: 10.1021/acs.jchemed.6b00954
– Name: ISSN
  Label: ISSN
  Group: ISSN
  Data: 0021-9584
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: An effective way of teaching undergraduates a full complement of research skills is through a multiweek advanced laboratory experiment. Here we outline a comprehensive set of experiments adapted from current primary literature focusing on organic and inorganic synthesis, catalysis, reactivity, and reaction kinetics. The catalyst, bis(2-(2'-hydroxyphenyl)-2-oxazoline)oxorhenium(V) tetrapentafluorophenylborate (1) is isolated through a multistep reaction starting with the formation of the ligand, 2-(2'-hydroxyphenyl)-2-oxazoline (2), followed by complexation of a Re-oxo precursor to form chlorobis(2-(2'-hydroxyphenyl)-2-oxazoline)oxorhenium(V) (3). Both Re(V)-oxo complexes are diamagnetic and allow for NMR analysis. Complex 1 is an air-stable and highly active catalyst for two reactions: (1) hydrosilylation of carbonyls and (2) hydrolysis of Et[subscript 3]SiH to form Et[subscript 3]SiOH and H[subscript 2] gas. Students monitor the evolution of hydrogen gas in the second reaction and use the data to investigate the reaction kinetics in order to obtain the complete rate law and the second-order rate constant for the catalytic reaction. The complete project provides a wealth of opportunities to focus on experimental skills, fundamental concepts in inorganic and organic chemistry, catalysis, reactivity, and experimental kinetics.
– Name: AbstractInfo
  Label: Abstractor
  Group: Ab
  Data: As Provided
– Name: Ref
  Label: Number of References
  Group: RefInfo
  Data: 22
– Name: DateEntry
  Label: Entry Date
  Group: Date
  Data: 2017
– Name: AN
  Label: Accession Number
  Group: ID
  Data: EJ1145960
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=eric&AN=EJ1145960
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1021/acs.jchemed.6b00954
    Languages:
      – Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 5
        StartPage: 790
    Subjects:
      – SubjectFull: Science Instruction
        Type: general
      – SubjectFull: College Science
        Type: general
      – SubjectFull: Undergraduate Study
        Type: general
      – SubjectFull: Chemistry
        Type: general
      – SubjectFull: Scientific Concepts
        Type: general
      – SubjectFull: Kinetics
        Type: general
      – SubjectFull: Spectroscopy
        Type: general
      – SubjectFull: Teaching Methods
        Type: general
      – SubjectFull: Laboratory Experiments
        Type: general
      – SubjectFull: Science Experiments
        Type: general
      – SubjectFull: Science Laboratories
        Type: general
      – SubjectFull: North Carolina
        Type: general
    Titles:
      – TitleFull: Oxorhenium Complexes for Catalytic Hydrosilylation and Hydrolytic Hydrogen Production: A Multiweek Advanced Laboratory Experiment for Undergraduate Students
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Ison, A.
      – PersonEntity:
          Name:
            NameFull: Ison, E. A.
      – PersonEntity:
          Name:
            NameFull: Perry, C. M.
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 06
              Type: published
              Y: 2017
          Identifiers:
            – Type: issn-print
              Value: 0021-9584
          Numbering:
            – Type: volume
              Value: 94
            – Type: issue
              Value: 6
          Titles:
            – TitleFull: Journal of Chemical Education
              Type: main
ResultId 1