Catalytic cycle for the asymmetric hydrogenation of prochiral ketones to chiral alcohols: direct hydride and proton transfer from chiral catalysts trans-Ru(H)(2)(diphosphine)(diamine) to ketones and direct addition of dihydrogen to the resulting hydridoamido complexes.

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Bibliographic Details
Title: Catalytic cycle for the asymmetric hydrogenation of prochiral ketones to chiral alcohols: direct hydride and proton transfer from chiral catalysts trans-Ru(H)(2)(diphosphine)(diamine) to ketones and direct addition of dihydrogen to the resulting hydridoamido complexes.
Authors: Abdur-Rashid K; Department of Chemistry, University of Toronto 80 Saint George Street, Toronto Ontario M5S 3H6, Canada., Faatz M, Lough AJ, Morris RH
Source: Journal of the American Chemical Society [J Am Chem Soc] 2001 Aug 01; Vol. 123 (30), pp. 7473-4.
Publication Type: Journal Article
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print Cited Medium: Print ISSN: 0002-7863 (Print) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: PubMed not MEDLINE
Database: MEDLINE Ultimate
Description
ISSN:0002-7863
DOI:10.1021/ja015902u