Catalytic cycle for the asymmetric hydrogenation of prochiral ketones to chiral alcohols: direct hydride and proton transfer from chiral catalysts trans-Ru(H)(2)(diphosphine)(diamine) to ketones and direct addition of dihydrogen to the resulting hydridoamido complexes.
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| Title: | Catalytic cycle for the asymmetric hydrogenation of prochiral ketones to chiral alcohols: direct hydride and proton transfer from chiral catalysts trans-Ru(H)(2)(diphosphine)(diamine) to ketones and direct addition of dihydrogen to the resulting hydridoamido complexes. |
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| Authors: | Abdur-Rashid K; Department of Chemistry, University of Toronto 80 Saint George Street, Toronto Ontario M5S 3H6, Canada., Faatz M, Lough AJ, Morris RH |
| Source: | Journal of the American Chemical Society [J Am Chem Soc] 2001 Aug 01; Vol. 123 (30), pp. 7473-4. |
| Publication Type: | Journal Article |
| Journal Info: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print Cited Medium: Print ISSN: 0002-7863 (Print) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: PubMed not MEDLINE |
| Database: | MEDLINE Ultimate |
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