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Experimental electronic structures of the FeIV=O bond in S=1 heme vs. nonheme sites: Effect of the porphyrin ligand.

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Title: Experimental electronic structures of the FeIV=O bond in S=1 heme vs. nonheme sites: Effect of the porphyrin ligand.
Authors: Braun A; Department of Chemistry, Stanford University, Stanford, CA 94305.; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Gee LB; Department of Chemistry, Stanford University, Stanford, CA 94305.; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Waters MDJ; Department of Chemistry, Stanford University, Stanford, CA 94305., Jose A; Department of Chemistry, Stanford University, Stanford, CA 94305., Baker ML; Department of Chemistry, Stanford University, Stanford, CA 94305.; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Mara MW; Department of Chemistry, Stanford University, Stanford, CA 94305.; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Babicz JT Jr; Department of Chemistry, Stanford University, Stanford, CA 94305., Ehudin MA; Department of Chemistry, Johns Hopkins University, Baltimore, MD 21218., Quist DA; Department of Chemistry, Johns Hopkins University, Baltimore, MD 21218., Zhou A; Department of Chemistry, University of Minnesota, Minneapolis, MN 55455., Kroll T; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Titus CJ; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025.; Department of Physics, Stanford University, Stanford., Lee SJ; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Nordlund D; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Sokaras D; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Yoda Y; Japan Synchrotron Radiation Research Institute, Sayo, Hyogo 679-5198, Japan., Kobayashi Y; Institute for Integrated Radiation and Nuclear Science, Kyoto University, Osaka 590-0494, Japan., Tamasaku K; RIKEN SPring-8 Center, RIKEN, Sayo, Hyogo 679-5148, Japan., Hedman B; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Hodgson KO; Department of Chemistry, Stanford University, Stanford, CA 94305.; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025., Karlin KD; Department of Chemistry, Johns Hopkins University, Baltimore, MD 21218., Que L Jr; Department of Chemistry, University of Minnesota, Minneapolis, MN 55455., Solomon EI; Department of Chemistry, Stanford University, Stanford, CA 94305.; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, CA 94025.
Source: Proceedings of the National Academy of Sciences of the United States of America [Proc Natl Acad Sci U S A] 2025 Feb 25; Vol. 122 (8), pp. e2420205122. Date of Electronic Publication: 2025 Feb 21.
Publication Type: Journal Article
Journal Info: Publisher: National Academy of Sciences Country of Publication: United States NLM ID: 7505876 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1091-6490 (Electronic) Linking ISSN: 00278424 NLM ISO Abbreviation: Proc Natl Acad Sci U S A Subsets: MEDLINE
Database: MEDLINE Ultimate
Description
ISSN:1091-6490
DOI:10.1073/pnas.2420205122