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Structural Mimics of Hydrocarbon Intermediates Reveal Counterclockwise Cyclization Pathways in the Sesquiterpene Synthases TmS and NcECS.

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Title: Structural Mimics of Hydrocarbon Intermediates Reveal Counterclockwise Cyclization Pathways in the Sesquiterpene Synthases TmS and NcECS.
Authors: Groll M; Center for Protein Assemblies, Department Bioscience, School of Natural Sciences, Technical University Munich, Ernst-Otto-Fischer-Straße 8, 85748 Garching, Germany., Li H; Kekulé Institute for Organic Chemistry and Biochemistry, University of Bonn, Gerhard-Domagk-Straße 1, 53121 Bonn, Germany., Troycke P; Center for Protein Assemblies, Department Bioscience, School of Natural Sciences, Technical University Munich, Ernst-Otto-Fischer-Straße 8, 85748 Garching, Germany., Kaila VRI; Department of Biochemistry and Biophysics, Stockholm University, Svante Arrhenius väg 16C, 10691 Stockholm, Sweden., Dickschat JS; Kekulé Institute for Organic Chemistry and Biochemistry, University of Bonn, Gerhard-Domagk-Straße 1, 53121 Bonn, Germany.
Source: Journal of the American Chemical Society [J Am Chem Soc] 2025 Dec 24; Vol. 147 (51), pp. 47742-47750. Date of Electronic Publication: 2025 Dec 10.
Publication Type: Journal Article
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: MEDLINE
Database: MEDLINE Ultimate
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  Data: <searchLink fieldCode="AU" term="%22Groll+M%22">Groll M</searchLink>; Center for Protein Assemblies, Department Bioscience, School of Natural Sciences, Technical University Munich, Ernst-Otto-Fischer-Straße 8, 85748 Garching, Germany.<br /><searchLink fieldCode="AU" term="%22Li+H%22">Li H</searchLink>; Kekulé Institute for Organic Chemistry and Biochemistry, University of Bonn, Gerhard-Domagk-Straße 1, 53121 Bonn, Germany.<br /><searchLink fieldCode="AU" term="%22Troycke+P%22">Troycke P</searchLink>; Center for Protein Assemblies, Department Bioscience, School of Natural Sciences, Technical University Munich, Ernst-Otto-Fischer-Straße 8, 85748 Garching, Germany.<br /><searchLink fieldCode="AU" term="%22Kaila+VRI%22">Kaila VRI</searchLink>; Department of Biochemistry and Biophysics, Stockholm University, Svante Arrhenius väg 16C, 10691 Stockholm, Sweden.<br /><searchLink fieldCode="AU" term="%22Dickschat+JS%22">Dickschat JS</searchLink>; Kekulé Institute for Organic Chemistry and Biochemistry, University of Bonn, Gerhard-Domagk-Straße 1, 53121 Bonn, Germany.
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  Data: <searchLink fieldCode="JN" term="%227503056%22">Journal of the American Chemical Society</searchLink> [J Am Chem Soc] 2025 Dec 24; Vol. 147 (51), pp. 47742-47750. <i>Date of Electronic Publication: </i>2025 Dec 10.
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        Value: 10.1021/jacs.5c17732
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