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Breaking the Aromaticity Trap: N-Silylation-Induced Formation of Stable 2,3-Dihydro-4-dialkylaminopyridin-1-iums.

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Title: Breaking the Aromaticity Trap: N-Silylation-Induced Formation of Stable 2,3-Dihydro-4-dialkylaminopyridin-1-iums.
Authors: Verkhov VA; St. Petersburg State University, Institute of Chemistry, Universitetskii pr. 26, 198504 St. Petersburg, Russian Federation., Yakubenko AA; St. Petersburg State University, Institute of Chemistry, Universitetskii pr. 26, 198504 St. Petersburg, Russian Federation., Begović B; Institute of Organic Chemistry, University of Regensburg, D-93053 Regensburg, Germany., Tupikina EY; St. Petersburg State University, Institute of Chemistry, Universitetskii pr. 26, 198504 St. Petersburg, Russian Federation., Antonov AS; Institute of Organic Chemistry, University of Regensburg, D-93053 Regensburg, Germany.
Source: The Journal of organic chemistry [J Org Chem] 2026 Jul 10; Vol. 91 (27), pp. 9252-9260. Date of Electronic Publication: 2026 Jun 25.
Publication Type: Journal Article
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 2985193R Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-6904 (Electronic) Linking ISSN: 00223263 NLM ISO Abbreviation: J Org Chem Subsets: MEDLINE; PubMed not MEDLINE
Database: MEDLINE Ultimate
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  Data: <searchLink fieldCode="AU" term="%22Verkhov+VA%22">Verkhov VA</searchLink>; St. Petersburg State University, Institute of Chemistry, Universitetskii pr. 26, 198504 St. Petersburg, Russian Federation.<br /><searchLink fieldCode="AU" term="%22Yakubenko+AA%22">Yakubenko AA</searchLink>; St. Petersburg State University, Institute of Chemistry, Universitetskii pr. 26, 198504 St. Petersburg, Russian Federation.<br /><searchLink fieldCode="AU" term="%22Begović+B%22">Begović B</searchLink>; Institute of Organic Chemistry, University of Regensburg, D-93053 Regensburg, Germany.<br /><searchLink fieldCode="AU" term="%22Tupikina+EY%22">Tupikina EY</searchLink>; St. Petersburg State University, Institute of Chemistry, Universitetskii pr. 26, 198504 St. Petersburg, Russian Federation.<br /><searchLink fieldCode="AU" term="%22Antonov+AS%22">Antonov AS</searchLink>; Institute of Organic Chemistry, University of Regensburg, D-93053 Regensburg, Germany.
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        Value: 10.1021/acs.joc.6c00105
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              Text: 2026 Jul 10
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