Bibliographic Details
| Title: |
[Cr4S(O2CCH3)8(H2O)4](BF4)2⋅H2O: Ferromagnetically Coupled Cr4S Cluster with Spin 6 Ground State. |
| Authors: |
BINO, A. (AUTHOR), JOHNSTON, D. C. (AUTHOR), GOSHORN, D. P. (AUTHOR), HALBERT, T. R. (AUTHOR), STIEFEL, E. I. (AUTHOR) |
| Source: |
Science (pre-March 2025). 9/16/1988, Vol. 241 Issue 4872, p1479-1481. 3p. 1 Diagram, 2 Charts, 3 Graphs. |
| Abstract: |
Data on the preparation, structure, and magnetism of the new complex [Cr4S(O2CCH3)8(H2O)4](BF4)2⋅H2O are presented. The metal-sulfur M4S core structure is similar to that found in M4S[S2As(CH3)2]6 (where M is cobalt or zinc) compounds and in beryllium basic acetate. However, the six-coordinate metal ions in the new Cr4S system distinguish it from these structures. The tetranuclear chromium complex is the first example of a new structural type. Its magnetic spin S = 6 ground state, a striking example of intramolecular ferromagnetic coupling, was determined by variable-temperature magnetic susceptibility measurements. Long-range antiferromagnetic intercluster ordering was found below 170 millikelvin. [ABSTRACT FROM AUTHOR] |
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| Database: |
Psychology and Behavioral Sciences Collection |
